Lesson 7. Pressure and Temperature & The Kelvin Scale

Carole Namowicz, Kathryn Lindeman, Umit Aslan
Chemistry
100 minutes
Sophomore Honors Chemistry
v2

Overview

Examining the effect of temperature on pressure

Standards

Next Generation Science Standards
  • NGSS Practice
    • Using Models
    • Using Mathematics

Activities

  • 1. Predicting the Change in Pressure
  • 2. Data Collection
  • 3. Data Analysis
  • 4. Pressure vs. Temperature
  • 5. The Kelvin Scale

Student Directions and Resources


In our last lesson, we began to explore pressure. We observed how changing both the number of particles and volume affected pressure. We saw that the number of gas particle and pressure have a direct relationship, while volume and pressure have an indirect (or inverse) relationship.

In this lesson, we will examine the effect of temperature on pressure.

We will also be introduced to a new temperature scale in which we will record the temperature of a gas.

1. Predicting the Change in Pressure


Below is a video of your instructor measuring the pressure of a sample of room temperature gas inside a flask. Pressure will be measured in units called kiloPascals (kPa). Watch the video and then answer the questions below.


Question 1.1

What is room temperature?



Question 1.2

What is the pressure of the room temperature gas?



Question 1.3

Predict how lowering the temperature of the gas will affect pressure. Also explain why you believe lowering temperature will have that effect based on your knowledge of gas particle movement and our definition of pressure.



Question 1.4

Predict how raising the temperature of the gas will affect pressure. Also explain why you believe raising temperature will have that effect based on your knowledge of gas particle movement and our definition of pressure.



2. Data Collection


Now your instructor will measure the pressure of a sample of gas inside a flask when the flask in submerged in both hot water and cold water. Pressure will be measured in units called kiloPascals (kPa). Complete the data table below after you view the video.


Question 2.1

Record temperature and pressure for all three gas temperatures measured.



3. Data Analysis


In order to analyze your acquired data, you will use Google Sheets. A template for Google Sheets has been created for you and can be found on Google Classroom.

  1. Notice the data table has already been created for you. Enter the temperature data at room temperature.
  2. Now enter temperature data for both cold/ice water and hot water.
  3. Now enter pressure data for all temperatures. A graph should appear in a box that previously said "No data".
  4. Add a trendline to the graph by opening the chart editor and clicking on “series” and clicking the “add trendline” box. The default trendline is linear which is what you want.
  5. Then answer the questions below.

Question 3.1

Upload an image of your graph by taking a screenshot and uploading it as a file into the answer box.

Screenshot Instructions

laptop: Use the snipping tool to highlight an area on the screen that can then be saved to your Google Drive.

Macbook: Command + shift + 4 then highlight the area on the screen that can be saved to your Google Drive.

Chromebook: Ctrl + switch key (button that allows you to switch between windows on top row) will allow you to save your screenshot in your Google Drive.

Upload files that are less than 5MB in size.
File Delete
Upload files to the space allocated by your teacher.


Question 3.2

Describe the relationship that you observe between pressure and temperature. Is it a direct or inverse relationship?



Question 3.3

At what temperature does the pressure of the gas equal zero?



Question 3.4

Do you think temperature can keep dropping indefinitely? Why or why not?



Question 3.5

What do you think a pressure of zero would indicate?



4. Pressure vs. Temperature


The graph you created on the last page should look very similar to the one shown below.

Notice the approximate temperature where pressure equals zero is -273 oC, this is no coincidence. -273 oC = 0 Kelvin, which is also known as absolute zero.

Absolute zero is the lowest theoretical temperature possible;  it is the temperature at which all particles cease movement. If particles are not moving, they cannot hit the walls of their container and therefore also have no pressure.

 


5. The Kelvin Scale


The Kelvin temperature scale is used when describing gases.  This is because the Kelvin scale is directly proportional to the kinetic energy of the gas particles. Thus, 0 K (absolute zero) means no kinetic energy. If particles have no kinetic energy, then they are not moving and cannot cause any pressure inside their container. This is why absolute zero (0 K) is also where pressure equals zero.

This temperature scale will become especially important when we begin gas calculations. Gas variable relationships we have explored can be expressed as mathematical equations. For example, as temperature decreases, so does volume, so if temperature is cut in half, volume will also be cut in half. This mathematical relationship will only hold true if the temperature is in Kelvin.

The Kelvin scale has no negative temperature as there can be no negative volumes, no negative pressures, and no negative number of particles.

The formulas to convert from the Celsius scale to Kelvin and back again are shown below. You will need them to complete the questions at the bottom of the page.

Celsius to Kelvin: K = oC + 273

Kelvin to Celsius: oC = K - 273


Question 5.1

Convert 0 oC to Kelvin.



Question 5.2

Convert 293 K to Celsius.



Question 5.3

What is 300 K in Celsius?



Question 5.4

Convert -55 oC to Kelvin.



Question 5.5

Convert 95 oC to Kelvin.



Question 5.6

Convert 22 oC to Kelvin.



Question 5.7

What is 0 K in Celsius?



Question 5.8

What is 43 oC in Kelvin?